Chemoselective Suzuki-Miyaura cross-coupling reactions of methyl 4-bromo-3-(trifluoromethylsulfonyloxy)-2-naphthoate

Khaddour, Z., Eleya, N., Akrawi, O. A., Hamdy, A. M., Patonay, T., Villinger, A., Langer, P.: Chemoselective Suzuki-Miyaura cross-coupling reactions of methyl 4-bromo-3-(trifluoromethylsulfonyloxy)-2-naphthoate.
Tetrahedron Lett. 54 (38), 5201-5203, 2013.

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title:

Chemoselective Suzuki-Miyaura cross-coupling reactions of methyl 4-bromo-3-(trifluoromethylsulfonyloxy)-2-naphthoate

authors:

Khaddour, Zien
Eleya, Nadi
Akrawi, Omer A.
Hamdy, Aws M.
Patonay Tamás
Villinger, Alexander
Langer, Peter

published:

2013

type:

article

genre:

research article/review article

journal:

Tetrahedron Letters (ISSN: 0040-4039)

language:

English

HAC:

Natural Sciences, Chemical Sciences

subjects:

Naphthalene, Chemoselectivity, Palladium, Catalysis, Suzuki-Miyaura reaction

abstract:

Arylated naphthalenes were prepared by Suzuki?Miyaura cross-coupling reactions of methyl 4-bromo-3-(trifluoromethylsulfonyloxy)-2-naphthoate. The reactions proceeded with very good chemoselectivity in favor of the triflate group, due to additive electronic ortho electronic effects.