Mechanism of the oscillatory decomposition of the dithionite ion in a flow reactor

Kovács, K. M., Rábai, G.: Mechanism of the oscillatory decomposition of the dithionite ion in a flow reactor.
Chem. Commun. 2 (7), 790-791, 2002.

doi DEA

Journal metrics:

Q1 Catalysis

D1 Ceramics and Composites

D1 Chemistry (miscellaneous)

D1 Electronic, Optical and Magnetic Materials

D1 Materials Chemistry

D1 Metals and Alloys

D1 Surfaces, Coatings and Films

title:

Mechanism of the oscillatory decomposition of the dithionite ion in a flow reactor

authors:

Kovács Klára, M.
Rábai Gyula

published:

2002

type:

article

genre:

research article/review article

journal:

Chemical Communications (ISSN: 1359-7345, 1364-548X)

language:

English

HAC:

Natural Sciences, Chemical Sciences

abstract:

A simple mechanism consisting of three protonation equilibria and seven redox reactions between sulfur species can describe the large amplitude-sustained temporal pH-oscillations observed during acid-induced decomposition of the dithionite ion in a continuous-flow stirred tank reactor (CSTR) in the temperature range 25-60.

projects:

25076